The Marvel Cinematic Universe

2008
Iron Man

Villains - Iron Monger (Jeff Bridges), Ten Rings (Various Actors)

The Incredible Hulk

Villains - Abomination (Tim Roth), General Ross (William Hurt)

2010
Iron Man 2

Villains - Whiplash (Mickey Rourke), Justin Hammer (Sam Rockwell)

2011
Thor

Villains - Loki (Tom Hiddleston), Frost Giants (Lots of other Actors)

Captain America: The First Avenger

Villains - Red Skull (Hugo Weaving), Arnim Zola (Toby Jones)

2012
 The Avengers

Villains - Loki (Tom Hiddleston), The Other (Alexis Denisof), 

2013
 Iron Man 3

Villains - Aldrich Killian (Guy Pearce), Eric Savin (James Badge Dale), Ellen Brandt (Stephanie Szostak)

<p style="font-weight:bold;">Thor: The Dark World

<p style="font-weight:bold;">Villains - Malekith (Christopher Eccleston), Kurse (Adewale Akinnuoye-Agbaje), Loki (Tom Hiddleston)

2014
<p style="font-weight:bold;"> <p style="font-weight:bold;">Captain America: The Winter Soldier

<p style="font-weight:bold;">Villains - Alexander Pierce (Robert Redford), The Winter Soldier (Sebastian Stan), Crossbones (Frank Grillo), Georges Batroc (Georges St-Pierre), Jasper Sitwell (Maximiliano Hernandez), Arnim Zola (Toby Jones),

<p style="font-weight:bold;"> Guardians Of The Galaxy

<p style="font-weight:bold;">Villains - Ronan (Lee Pace), Nebula (Karen Gillan), Thanos (Josh Brolin), The Other (Alexis Denisof), Korath (Djimon Hounsou), The Collector (Benicio del Toro),  <h3 style="font-weight:bold;">2015

<p style="font-weight:bold;">Avengers: Age Of Ultron

<p style="font-weight:bold;">Villains - Ultron (James Spader), Baron von Strucker (Thomas Kretschmann), Ant-Man

<p style="font-weight:bold;">Ant-Man

<p style="font-weight:bold;">Villains - Yellowjaket (Corey Stoll), Crossfire (David Dastmalchian)

<p style="font-weight:bold;">2016

<p style="font-weight:bold;">Captain America: Fallen Son

<p style="font-weight:bold;">Villains - \ Crossbones (Frank Grillo),