The Marvel Cinematic Universe

2008
 Iron Man

Villains - Iron Monger (Jeff Bridges), Ten Rings (Various Actors)

The Incredible Hulk

Villains - Abomination (Tim Roth), General Ross (William Hurt)

2010
  

Iron Man 2

Villains - Whiplash (Mickey Rourke), Justin Hammer (Sam Rockwell)

2011
  

Thor

Villains - Loki (Tom Hiddleston), Frost Giants (Various Actors)

Captain America: The First Avenger

Villains - Red Skull (Hugo Weaving), Arnim Zola (Toby Jones)

2012
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<p style="font-weight:bold;">The Avengers

<p style="font-weight:bold;">Villains - Loki (Tom Hiddleston), The Other (Alexis Denisof), 

2013
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<p style="font-weight:bold;">Iron Man 3

<p style="font-weight:bold;">Villains - Aldrich Killian (Guy Pearce), Eric Savin (James Badge Dale), Ellen Brandt (Stephanie Szostak)

<p style="font-weight:bold;">Thor: The Dark World

<p style="font-weight:bold;">Villains - Malekith (Christopher Eccleston), Kurse (Adewale Akinnuoye-Agbaje), Loki (Tom Hiddleston)

2014
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<p style="font-weight:bold;">Captain America: The Winter Soldier

<p style="font-weight:bold;">Villains - Alexander Pierce (Robert Redford), The Winter Soldier (Sebastian Stan), Crossbones (Frank Grillo), Georges Batroc (Georges St-Pierre), Jasper Sitwell (Maximiliano Hernandez), Arnim Zola (Toby Jones), Baron von Strucker (Thomas Kretschmann)