The Marvel Cinematic Universe

2008
Iron Man

Heroes - Iron Man (Robert Downey Jr.)

Villains - Iron Monger (Jeff Bridges), Ten Rings (Various Actors)

The Incredible Hulk

Villains - Abomination (Tim Roth), General Ross (William Hurt)

2010
Iron Man 2

Villains - Whiplash (Mickey Rourke), Justin Hammer (Sam Rockwell)

2011
Thor

Villains - Loki (Tom Hiddleston), Frost Giants (Lots of other Actors)

Captain America: The First Avenger

Villains - Red Skull (Hugo Weaving), Arnim Zola (Toby Jones)

2012
The Avengers Villains - Loki (Tom Hiddleston), The Other (Alexis Denisof), 

The Amazing Spider-Man 

Villains - The Lizard (Rhys Ifans)

2013
 Iron Man 3

Villains - Aldrich Killian (Guy Pearce), Eric Savin (James Badge Dale), Ellen Brandt (Stephanie Szostak)

Thor: The Dark World

<p style="font-weight:bold;">Villains - Malekith (Christopher Eccleston), Kurse (Adewale Akinnuoye-Agbaje), Loki (Tom Hiddleston)

2014
<p style="font-weight:bold;"> <p style="font-weight:bold;">Captain America: The Winter Soldier

<p style="font-weight:bold;">Villains - Alexander Pierce (Robert Redford), The Winter Soldier (Sebastian Stan), Crossbones (Frank Grillo), Georges Batroc (Georges St-Pierre), Jasper Sitwell (Maximiliano Hernandez), Arnim Zola (Toby Jones),

The Amazing Spider-Man 2

Villains - Green Goblin (Dane DeHaan), Rhino (Paul Giamatti), Electro (Jamie Foxx)

<p style="font-weight:bold;"> Guardians Of The Galaxy

<p style="font-weight:bold;">Villains - Ronan (Lee Pace), Nebula (Karen Gillan), Thanos (Josh Brolin), The Other (Alexis Denisof), Korath (Djimon Hounsou), The Collector (Benicio del Toro),  <h3 style="font-weight:bold;">2015

<p style="font-weight:bold;">Avengers: Age Of Ultron

<p style="font-weight:bold;">Villains - Ultron (James Spader), Baron von Strucker (Thomas Kretschmann), Ant-Man <h3 style="font-weight:bold;">Phase 3

<p style="font-weight:bold;">Ant-Man

<p style="font-weight:bold;">Heroes - Ant-Man (Paul Rudd), The Wasp (Evangeline Lilly)

<p style="font-weight:bold;">Villains - Yellowjaket (Corey Stoll), Crossfire (David Dastmalchian)

<h3 style="font-weight:bold;">2016

<p style="font-weight:bold;">Captain America: Civil War

<p style="font-weight:bold;">Heroes - Captain America (Chris Evans), The Winter Soldier (Sebastain Stan),  Black Widow (Scarlett Johansson), Hawkeye (Jeremy Rener), Agents of S.H.I.E.L.D (Various Actors), Iron Man (Robert Downey Jr.), Mockingbird (Adrianne Palicki), Captain Marvel (TBA)

<p style="font-weight:bold;">Villains - Crossbones (Frank Grillo), Red Skull (Hugo Weaving),  Baron Zemo  (TBA), M.O.D.O.K. (TBA)

<p style="font-weight:bold;">Doctor Strange

<p style="font-weight:bold;">Heores - Doctor Strange (Joaquin Phoenix)

<p style="font-weight:bold;">Villains - Baron Mordo (TBA), Dormammu (TBA)

2017
<p style="font-weight:bold;">Thor: Ragnarok

<p style="font-weight:bold;">Heroes - Thor (Chris Hemsworth), Beta Ray Bill (TBA)

Villains - Surtur (TBA), Enchantress (TBA), Excecutioner (TBA), Loki (Tom Hiddleston)

Guardians Of The Galaxy: War Of Kings

<p style="font-weight:bold;">Heroes - Star-Lord (Chris Pratt), Gamora (Zoe Saldana), Drax the Destoryer (Dave Bautista), Rocket Raccoon (Bradley Cooper), Groot (Vin Diesel), Adam Warlock (TBA)

<p style="font-weight:bold;">Villains - Korvac (TBA), Kang the Conqueror (TBA) Nebula (Karen Gillian), The Collector (Benicio del Toro)

<p style="font-weight:bold;"> Black Panther

<p style="font-weight:bold;">Heroes - Black Panther (Chadwick Boseman)

<p style="font-weight:bold;">Villains - Erik Killmonger (Raw Leiba), Klaw (TBA)

2018
<p style="font-weight:bold;">

<p style="font-weight:bold;">Avengers: The Infinity Gauntlet

<p style="font-weight:bold;">Villains - Thanos (Josh Brolin), Baron von Strucker (Thomas Kretschman)

<p style="font-weight:bold;">Hurt)

<p style="font-weight:bold;">

<p style="font-weight:bold;">World War Hulk

<p style="font-weight:bold;">Heroes - Hulk (CGI Human: Mark Ruaffalo)

<p style="font-weight:bold;">Villians - TBA

<p style="font-weight:bold;">

<h3 style="font-weight:bold;">2019 The Inhumans

Heroes - Black Bolt (Vin Diesal),  Medusa (Emily Blunt), Crystal (Saorise Ronan), Karnak (Luke Evans), Gorgon (Joe Mangiello), Triton (Alexander Skarsgard), Maximus (Iwan Rohen), Lockjaw (Bradley Dee Baker)

Villians - Skrulls (TBA)

Unknown Releases
Ms. Marvel

Heroes - Ms. Marvel (Eden Sher), Captain Marvel (TBA)

Villians - Kree (TBA)

Black Widow 

<p style="font-weight:bold;">Heroes - Black Widow (Scarlett Johansson), Hawkeye (Jeremy Rener), Bucky Barnes (Sebastain Stan)

<p style="font-weight:bold;">Villains - HYDRA (Various Actors), Madame Hydra (TBA)

The Indestructible Hulk Heroes - Hulk (Mark Ruffalo), She-Hulk (Gretel Ashzinger), Doc Samson (Ty Burrell)

Villians - The Leader (Tim Blake Nelson), Red-Hulk (William 

Nova

Heroes - Nova (TBA)

Villians - Diamondhead (TBA), Sphinx (TBA)

Nick Fury

Heroes - Nick Fury (Samuel L. Jackson)

Villians - Baron von Struker (Thomas Kretchmann)

Guardians of the Galaxy 3

Heroes - Guardians of the Galaxy (Various Actors)

Villians - TBA

Black Cat

 Heroes: Black Cat (Felicity Jones) Villains: Kingpin (Vincent D' 

Possible Movies
Vision

Ka-Zar (if not in X-Men universe)

Blade

The Punisher

Ghost Rider

Quasar

She-Hulk

2014
Agents of S.H.I.E.L.D 

Heroes - S.H.I.E.L.D (various actors)

Villlians - HYDRA (various actors)

2015
Agent Carter

Heroes - Peggy Carter (Hayley Atwell)

Villians - HYDRA (various actors)

2015
Daredevil

Heroes - Daredevil (Charlie Cox)

Villians - Kingpin (Vincent D'Onoforio), Bullseye (Craig Henningsen)

AKA Jessica Jones

Heroes - Jessica Jones (TBA), Luke Cage (Mars Crain)

Villians - Purple Man(TBA)

2016
Luke Cage

Heroes - Luke Cage (Mars Crain)

Villians - Chemistro (TBA)

Iron Fist

Heroes - Iron Fist (TBA)

Villians - Master Khan (TBA)

The Defenders

Heroes - The Defenders - Jessica Jones (TBA), Iron Fist (TBA), Luke Cage (Mars Crain), Daredevil (Charlie Cox)

Villians - Mephisto (TBA)

Characters
Avengers The Defenders
 * Chris Evans as Captain America (decreased)
 * Sabastain Stan as Captain America (current)
 * Robert Downey Jr. as Iron Man
 * Chris Hemsworth as Thor
 * Mark Ruffalo as Hulk
 * Scarlett Johansson as Black Widow
 * Jeremy Renner as Hawkeye
 * Elizabeth Olsen as Scarlet Witch
 * Aaron Taylor-Johnson as Quicksilver
 * Paul Bettany as The Vision
 * Chadwick Boseman as Black Panther
 * Joaquin Phonenix as Doctor Strange
 * Evangeline Lily as Wasp
 * Paul Rudd as Ant-Man
 * Eden Sher as Ms. Marvel
 * Anthony Mackie as Falcon
 * Don Cheadle as Iron Patriot
 * Chris Pratt as Star-Lord
 * Zoe Saldana as Gamora
 * Dave Bautista as Drax
 * Vin Diesel as Groot
 * Bradley Cooper as Rocket Raccoon
 * Charlie Cox as Daredevil
 * TBA as Jessica Jones
 * TBA as Iron Fist
 * Mars Crain as Luke Cage

Guardians of the Galaxy

 * Chris Pratt as Star-Lord
 * Zoe Saldana as Gamora
 * Dave Bautista as Drax
 * Bradley Cooper as Rocket Raccoon
 * Vin Diesal as Groot
 * TBA as Adam Warlock