The Marvel Cinematic Universe

2008
Iron Man

Heroes - Iron Man (Robert Downey Jr.)

Villains - Iron Monger (Jeff Bridges), Ten Rings (Various Actors)

The Incredible Hulk

Villains - Abomination (Tim Roth), General Ross (William Hurt)

2010
Iron Man 2

Villains - Whiplash (Mickey Rourke), Justin Hammer (Sam Rockwell)

2011
Thor

Villains - Loki (Tom Hiddleston), Frost Giants (Lots of other Actors)

Captain America: The First Avenger

Villains - Red Skull (Hugo Weaving), Arnim Zola (Toby Jones)

2012
The Avengers Villains - Loki (Tom Hiddleston), The Other (Alexis Denisof), 

2013
 Iron Man 3

Villains - Aldrich Killian (Guy Pearce), Eric Savin (James Badge Dale), Ellen Brandt (Stephanie Szostak)

Thor: The Dark World

<p style="font-weight:bold;">Villains - Malekith (Christopher Eccleston), Kurse (Adewale Akinnuoye-Agbaje), Loki (Tom Hiddleston)

2014
<p style="font-weight:bold;"> <p style="font-weight:bold;">Captain America: The Winter Soldier

<p style="font-weight:bold;">Villains - Alexander Pierce (Robert Redford), The Winter Soldier (Sebastian Stan), Crossbones (Frank Grillo), Georges Batroc (Georges St-Pierre), Jasper Sitwell (Maximiliano Hernandez), Arnim Zola (Toby Jones),

<p style="font-weight:bold;"> Guardians Of The Galaxy

<p style="font-weight:bold;">Villains - Ronan (Lee Pace), Nebula (Karen Gillan), Thanos (Josh Brolin), The Other (Alexis Denisof), Korath (Djimon Hounsou), The Collector (Benicio del Toro),  <h3 style="font-weight:bold;">2015

<p style="font-weight:bold;">Avengers: Age Of Ultron

<p style="font-weight:bold;">Villains - Ultron (James Spader), Baron von Strucker (Thomas Kretschmann), Ant-Man

<p style="font-weight:bold;">Ant-Man

<p style="font-weight:bold;">Heroes - Ant-Man (Paul Rudd), The Wasp (Evangeline Lilly)

<p style="font-weight:bold;">Villains - Yellowjaket (Corey Stoll), Crossfire (David Dastmalchian)

<h3 style="font-weight:bold;">2016

<p style="font-weight:bold;">Captain America: Fallen Son

<p style="font-weight:bold;">Heroes - Captain America (Chris Evans), The Winter Soldier (Sebastain Stan),  Black Widow (Scarlett Johansson), Hawkeye (Jeremy Rener), Agents of S.H.I.E.L.D (Various Actors)

<p style="font-weight:bold;">Villains - Crossbones (Frank Grillo), Red Skull (Hugo Weaving),  Baron Zemo  (TBA)

<p style="font-weight:bold;">Doctor Strange

<p style="font-weight:bold;">Heores - Doctor Strange (Joaquin Phoenix)

<p style="font-weight:bold;">Villains - Baron Mordo (TBA), Dormammu (TBA)

2017
<p style="font-weight:bold;">Thor: Ragnarok

<p style="font-weight:bold;">Heroes - Thor (Chris Hemsworth), Beta Ray Bill (TBA)

<p style="font-weight:bold;">Villains - Surtur (TBA), Enchantress (TBA), Excecutioner (TBA), Loki (Tom Hiddleston) 

<p style="font-weight:bold;">Black Panther

<p style="font-weight:bold;">Villains - Erik Killmonger (Raw Leiba), Klaw (TBA)

2018
<p style="font-weight:bold;">Avengers: The Infinity Gauntlet

<p style="font-weight:bold;">Villains - Thanos (Josh Brolin), Baron von Strucker (Thomas Kretschman)

<p style="font-weight:bold;">Guardians Of The Galaxy: War Of Kings

<p style="font-weight:bold;">Heroes - Star-Lord (Chris Pratt), Gamora (Zoe Saldana), Drax the Destoryer (Dave Bautista), Rocket Raccoon (Bradley Cooper), Groot (Vin Diesel)

<p style="font-weight:bold;">Villains - Korvac (TBA), Nebula (Karen Gillian), The Collector (Benicio del Toro) 

<p style="font-weight:bold;">Black Widow

<p style="font-weight:bold;">Heroes - Black Widow (Scarlett Johansson), Hawkeye (Jeremy Rener), Bucky Barnes (Sebastain Stan)

<p style="font-weight:bold;">Villains - HYDRA (Various Actors), Madame Hydra (TBA)

The Indestructible Hulk
Heroes - Hulk (Mark Ruffalo), She-Hulk (Gretel Ashzinger), Doc Samson (Ty Burrell)

Villians - The Leader (Tim Blake Nelson), Red-Hulk (William Hurt)

Unknown Releases
Ms. Marvel

Heroes - Ms. Marvel (Eden Sher), Captain Marvel (TBA)

Villians - TBA

Nova

Heroes - Nova (TBA)

Villians - Diamondhead (TBA), Sphinx (TBA)

Nick Fury

Heroes - Nick Fury (Samuel L. Jackson)

Villians - Baron von Struker (Thomas Kretchmann)

Possible Movies
Vision

Ka-Zar (if not in X-Men universe)

The Inhumans (If not in X-Men Universe)\

Blade

The Punisher

Ghost Rider

Quasar

She-Hulk

Midnight Sons