The Marvel Cinematic Universe

2008
Iron Man

Heroes - Iron Man (Robert Downey Jr.)

Villains - Iron Monger (Jeff Bridges), Ten Rings (Various Actors)

The Incredible Hulk

Villains - Abomination (Tim Roth), General Ross (William Hurt)

2010
Iron Man 2

Villains - Whiplash (Mickey Rourke), Justin Hammer (Sam Rockwell)

2011
Thor

Villains - Loki (Tom Hiddleston), Frost Giants (Lots of other Actors)

Captain America: The First Avenger

Villains - Red Skull (Hugo Weaving), Arnim Zola (Toby Jones)

2012
The Avengers Villains - Loki (Tom Hiddleston), The Other (Alexis Denisof), 

2013
 Iron Man 3

Villains - Aldrich Killian (Guy Pearce), Eric Savin (James Badge Dale), Ellen Brandt (Stephanie Szostak)

Thor: The Dark World

<p style="font-weight:bold;">Villains - Malekith (Christopher Eccleston), Kurse (Adewale Akinnuoye-Agbaje), Loki (Tom Hiddleston)

2014
<p style="font-weight:bold;"> <p style="font-weight:bold;">Captain America: The Winter Soldier

<p style="font-weight:bold;">Villains - Alexander Pierce (Robert Redford), The Winter Soldier (Sebastian Stan), Crossbones (Frank Grillo), Georges Batroc (Georges St-Pierre), Jasper Sitwell (Maximiliano Hernandez), Arnim Zola (Toby Jones),

<p style="font-weight:bold;"> Guardians Of The Galaxy

<p style="font-weight:bold;">Villains - Ronan (Lee Pace), Nebula (Karen Gillan), Thanos (Josh Brolin), The Other (Alexis Denisof), Korath (Djimon Hounsou), The Collector (Benicio del Toro),  <h3 style="font-weight:bold;">2015

<p style="font-weight:bold;">Avengers: Age Of Ultron

<p style="font-weight:bold;">Villains - Ultron (James Spader), Baron von Strucker (Thomas Kretschmann), Ant-Man <h3 style="font-weight:bold;">Phase 3

<p style="font-weight:bold;">Ant-Man

<p style="font-weight:bold;">Heroes - Ant-Man (Paul Rudd), The Wasp (Evangeline Lilly)

<p style="font-weight:bold;">Villains - Yellowjaket (Corey Stoll), Crossfire (David Dastmalchian)

<h3 style="font-weight:bold;">2016

<p style="font-weight:bold;">Captain America: Fallen Son

<p style="font-weight:bold;">Heroes - Captain America (Chris Evans), The Winter Soldier (Sebastain Stan),  Black Widow (Scarlett Johansson), Hawkeye (Jeremy Rener), Agents of S.H.I.E.L.D (Various Actors)

<p style="font-weight:bold;">Villains - Crossbones (Frank Grillo), Red Skull (Hugo Weaving),  Baron Zemo  (TBA)

<p style="font-weight:bold;">Doctor Strange

<p style="font-weight:bold;">Heores - Doctor Strange (Joaquin Phoenix)

<p style="font-weight:bold;">Villains - Baron Mordo (TBA), Dormammu (TBA)

2017
<p style="font-weight:bold;">Thor: Ragnarok

<p style="font-weight:bold;">Heroes - Thor (Chris Hemsworth), Beta Ray Bill (TBA)

Villains - Surtur (TBA), Enchantress (TBA), Excecutioner (TBA), Loki (Tom Hiddleston)

Guardians Of The Galaxy: War Of Kings

<p style="font-weight:bold;">Heroes - Star-Lord (Chris Pratt), Gamora (Zoe Saldana), Drax the Destoryer (Dave Bautista), Rocket Raccoon (Bradley Cooper), Groot (Vin Diesel), Adam Warlock (TBA)

<p style="font-weight:bold;">Villains - Korvac (TBA), Kang the Conqueror (TBA) Nebula (Karen Gillian), The Collector (Benicio del Toro)

<p style="font-weight:bold;"> Black Panther

<p style="font-weight:bold;">Heroes - Black Panther (Chadwick Boseman)

<p style="font-weight:bold;">Villains - Erik Killmonger (Raw Leiba), Klaw (TBA)

2018
<p style="font-weight:bold;">

<p style="font-weight:bold;">Avengers: The Infinity Gauntlet

<p style="font-weight:bold;">Villains - Thanos (Josh Brolin), Baron von Strucker (Thomas Kretschman)

<p style="font-weight:bold;">Hurt)

<p style="font-weight:bold;">

<p style="font-weight:bold;">World War Hulk

<p style="font-weight:bold;">Heroes - Hulk (CGI Human: Mark Ruaffalo)

<p style="font-weight:bold;">Villians - TBA

<p style="font-weight:bold;">

<h3 style="font-weight:bold;">2019 The Inhumans

Heroes - Black Bolt (Vin Diesal),  Medusa (TBA), Crystal (TBA), Karnak (TBA), Gorgon (TBA), Triton (TBA)

Villians - Skrulls (TBA)

Unknown Releases
Ms. Marvel

Heroes - Ms. Marvel (Eden Sher), Captain Marvel (TBA)

Villians - Kree (TBA)

Black Widow 

<p style="font-weight:bold;">Heroes - Black Widow (Scarlett Johansson), Hawkeye (Jeremy Rener), Bucky Barnes (Sebastain Stan)

<p style="font-weight:bold;">Villains - HYDRA (Various Actors), Madame Hydra (TBA)

The Indestructible Hulk Heroes - Hulk (Mark Ruffalo), She-Hulk (Gretel Ashzinger), Doc Samson (Ty Burrell)

Villians - The Leader (Tim Blake Nelson), Red-Hulk (William 

Nova

Heroes - Nova (TBA)

Villians - Diamondhead (TBA), Sphinx (TBA)

Nick Fury

Heroes - Nick Fury (Samuel L. Jackson)

Villians - Baron von Struker (Thomas Kretchmann)

Midnight Sons

Heroes - TBA

Villians - Blackout (TBA), Nightmare (TBA)

Guardians of the Galaxy 3

Heroes - Guardians of the Galaxy (Various Actors)

Villians - Shuma-Gorath

Possible Movies
Vision

Ka-Zar (if not in X-Men universe)

Blade

The Punisher

Ghost Rider

Quasar

She-Hulk

2014
Agents of S.H.I.E.L.D 

Heroes - S.H.I.E.L.D (various actors)

Villlians - HYDRA (various actors)

2015
Agent Carter

Heroes - Peggy Carter (Hayley Atwell)

Villians - HYDRA (various actors)

2015
Daredevil

Heroes - Daredevil (Charlie Cox)

Villians - Kingpin (Vincent D'Onoforio), Bullseye (Craig Henningsen)

AKA Jessica Jones

Heroes - Jessica Jones (TBA), Luke Cage (Mars Crain)

Villians - Purple Man(TBA)

2016
Luke Cage

Heroes - Luke Cage (Mars Crain)

Villians - Chemistro (TBA)

Iron Fist

Heroes - Iron Fist (TBA)

Villians - Master Khan (TBA)

The Defenders

Heroes - The Defenders - Jessica Jones (TBA), Iron Fist (TBA), Luke Cage (Mars Crain), Daredevil (Charlie Cox)

Villians - Mephisto (TBA)

Phase 4
Punisher

Heroes - Punisher (TBA)

Villians - Jigsaw (TBA)

Moon Knight

Heroes - Moon Knight (TBA)

Villians - Bushman (TBA)

2019
Deathlok

Heroes - Deathlok (TBA)

Villians - Fixer (TBA)

Spider-Woman

Heroes - Spider-Woman

Villians - Madame Hydra

Characters
Avengers The Defenders
 * Chris Evans as Captain America (decreased)
 * Sabastain Stan as Captain America (current)
 * Robert Downey Jr. as Iron Man
 * Chris Hemsworth as Thor
 * Mark Ruffalo as Hulk
 * Scarlett Johansson as Black Widow
 * Jeremy Renner as Hawkeye
 * Elizabeth Olsen as Scarlet Witch
 * Aaron Taylor-Johnson as Quicksilver
 * Paul Bettany as The Vision
 * Chadwick Boseman as Black Panther
 * Joaquin Phonenix as Doctor Strange
 * Evangeline Lily as Wasp
 * Paul Rudd as Ant-Man
 * Eden Sher as Ms. Marvel
 * Anthony Mackie as Falcon
 * Don Cheadle as Iron Patriot
 * Chris Pratt as Star-Lord
 * Zoe Saldana as Gamora
 * Dave Bautista as Drax
 * Vin Diesel as Groot
 * Bradley Cooper as Rocket Raccoon
 * Charlie Cox as Daredevil
 * TBA as Jessica Jones
 * TBA as Iron Fist
 * Mars Crain as Luke Cage

Guardians of the Galaxy

 * Chris Pratt as Star-Lord
 * Zoe Saldana as Gamora
 * Dave Bautista as Drax
 * Bradley Cooper as Rocket Raccoon
 * Vin Diesal as Groot
 * TBA as Adam Warlock