The Amazing Spider-Man (2012-2020 film series)

The Amazing Spider-Man (2012 film)
Teenage social outcast Peter Parker spends his days trying to unravel the mystery of his own past and winning the heart of his high school crush, Gwen Stacy. Peter discovers a mysterious briefcase belonging to his father, who abandoned him when he was a child, which leads him to his dad's former partner, Dr. Conners. The discovery of his father's secret will ultimately shape his destiny of becoming "Spider-Man" and brings him face to face with Connors' villainous alter ego, the Lizard.
 * Peter Parker/Spider-Man
 * Gwen Stacy
 * Dr. Curt Conners/The Lizard
 * Captain George Stacy
 * May Parker
 * Ben Parker
 * Dr. Ratha
 * Flash Thompson
 * Richard Parker
 * Mary Parker

The Amazing Spider-Man 2 (2014 film)
Peter Parker runs the Gauntlet as the mysterious company Oscorp sends out villains to fight him, impacting on his life.
 * Peter Parker/Spider-Man
 * Gwen Stacy
 * Aleskei Sytsevich/The Rhino
 * Captain George Stacy
 * May Parker
 * Harry Osborn
 * Norman Osborn/Green Goblin
 * Flash Thompson
 * Maximillion Dillion/Electro
 * Donald Menken

The Amazing Spider-Man 3 (2016 film)
Peter's young wife, Gwen died at the hands of the Green Goblin, so Peter swears to his life to hunt down Gwen's killer. But when Oscorp gets a sample of the symbiote after John Jameson discovered it in space, Peter finds out that him and new friend, Eddie Brock's, dads worked on that calling it "The Inheritance" to cure the sick. Parker puts it on, while trying to get to Goblin, but he sends in 2 villains to distract Spidey.
 * Peter Parker/Spider-Man
 * Mary Jane Watson
 * Harry Osborn
 * Felicia Hardy/Black Cat
 * Adrien Toomes/Vulture
 * Herman Scultz/Shocker
 * J. Jonah Jameson
 * May Parker
 * Robbie Robertson
 * Flash Thompson
 * Norman Osborn
 * Betty Brant
 * Wilson Fisk/Kingpin
 * Roderick Kingsley/Hobgoblin
 * Eddie Brock
 * Anne Weying
 * John Jameson
 * Cletus Cassidy
 * John Jameson

Venom (2017 film)
Eugene Flash Thompson is struggling with life as a 20 year old College student as he gets an application to the US Military. But when Oscorp symbiote product bonds with him, he plans to use it to protect the people of New York with help of Spider-man. He uses it to stop Cletus Cassidy/Carnage from infecting Manhattan.
 * Flash Thompson/Agent Venom
 * Eddie Brock
 * Cletus Cassidy/Carnage
 * Peter Parker/Spider-Man
 * J. Jonah Jameson
 * Betty Brant
 * Mac Gargan/Scorpion
 * Donald Menken
 * Harry Osborn

The Amazing Spider-Man 4 (2018 film)
After the huge infection Carnage caused in New York, Spider-Man and other Avengers members and S.H.I.E.L.D agents fight Eddie Brock, alter ego as Venom and Anne Weying, bonding with symbiote named, Toxin.
 * Peter Parker/Spider-Man
 * Eddie Brock/Venom
 * Anne Weying/Toxin
 * Wilson Fisk/Kingpin
 * Mary Jane Watson
 * Harry Osborn
 * Norman Osborn (cameo)
 * J. Jonah Jameson
 * Betty Brant
 * Robbie Robertson
 * Ned Leeds
 * Luke Cage/Power Man
 * James Howlett/Wolverine
 * Moonknight
 * Nick Fury
 * Natasha Romanoff/Black Widow

The Amazing Spider-Man 5 (2020 film)
His life as a vigilante has been long. Peter notices that Wilson Fisk, Silvermane Manfredi, and The Rose send out the Sinister Six to destroy Spider-Man, consisting of the enemies he fought in the past. Now Peter's last battle for his life, Death or Live?
 * Peter Parker/Spider-Man
 * Mary Jane Watson
 * Norman Osborn/Green Goblin (Sinister Six leader)
 * Wilson Fisk/Kingpin (crime boss who sent out S6 to destroy the Wall Crawler)
 * J. Jonah Jameson
 * The Rose (Kingpin's heir)
 * Silvermane Manfredi (most powerful crime boss ever)
 * Maximillion Dillon/Electro (Big part of the villain team)
 * Aleskei Stysevich/Rhino (Sinister Six member)
 * Adrien Toomes/Vulture (Sinister Six member)
 * Max Gargan/Scorpion (Sinister Six member)
 * Flash Thompson/Agent Venom (helps Spidey defeat the Six, but Flash soon dies)
 * Felicia Hardy/Black Cat (helps Peter fight the battle of his life)
 * Curt Conners/Lizard (forced to join the Six)