The Marvel Cinematic Universe

2008
Iron Man

Heroes - Iron Man (Robert Downey Jr.),

Villains - Iron Monger (Jeff Bridges), Ten Rings (Various Actors)

Other Characters - James Rhodes (Terrence Howard), Pepper Potts (Gwyneth Paltrow)

The Incredible Hulk

Heroes - Hulk (Edward Norton)

Villains - Abomination (Tim Roth), General Ross (William Hurt) Other Characters - Betty Ross (Liv Tyler)

2010
Iron Man 2 Heroes - Iron Man (Robert Downey Jr.), War Machine (Don Cheadle), Nick Fury (Samuel L. Jackson), Black Widow (Scarlett Johansson)

Villains - Whiplash (Mickey Rourke), Justin Hammer (Sam Rockwell)

2011
Thor Heroes - Thor (Chris Hemsworth)

Villains - Loki (Tom Hiddleston), Frost Giants (Various Actors)

Other Characters - Jane Foster (Natalie Portman), Odin (Anthony Hopkins), Darcy Lewis (Kat Dennings), Sif (Jamie Alexander), Laufey ( Colm Fore), Fandral (Joshua Dallas), Hogun (Tadanobu Asano), Heimdall (Idris Elba), Frigga (Rene Russo)

Captain America: The First Avenger

Heroes - Captain America (Chris Evans)

Villains - Red Skull (Hugo Weaving), Arnim Zola (Toby Jones) Other Characters - Peggy Carter (Hayley Atwell), Bucky Barnes (Sebastain Stan),

2012
The Avengers Heroes - Iron Man (Robert Downey Jr.), Captain America (Chris Evans), Hulk (Mark Ruffalo), Thor (Chris Hemsworth), Black Widow (Scarlett Johansson), Hawkeye (Jeremy Renner), Nick Fury (Samuel L. Jackson), Maria Hill (Cobie Smulders)

Villains - Loki (Tom Hiddleston), The Other (Alexis Denisof)

Other Characters: Pepper Potts (Gwyneth Paltrow), Phil Coulson (Gregg Clark), Erik Slevig (Stellan Skarsgard), J.A.R.V.I.S (Paul Bettany)

The Amazing Spider-Man

Heroes - Spider-Man (Andrew Garfield)

Villains - The Lizard (Rhys Ifans)

Other Characters - Gwen Stacy (Emma Stone), May Parker (Sally Field), George Stacy (Denis Leary)

Phase 2

2013
 Iron Man 3 Heroes - Iron Man (Robert Downey Jr.), Iron Patriot (Don Cheadle)

Villains - Aldrich Killian (Guy Pearce), Eric Savin (James Badge Dale), Ellen Brandt (Stephanie Szostak)

Thor: The Dark World

Heroes - Thor (Chris Hemsworth), Sif (Jamie Alexander), Volstagg (Ray Stevenson), Fandral (Zachary Levi), Hogun (Tadanobu Asano)

Villains - Malekith (Christopher Eccleston), Kurse (Adewale Akinnuoye-Agbaje), Loki (Tom Hiddleston)

Other Characters - Jane Foster (Natalie Portman), Odin (Anthony Hopkins), Frigga (Rene Russo), Darcy Lewis (Kat Dennings)

2014
<p style="font-weight:bold;"> <p style="font-weight:bold;">Captain America: The Winter Soldier Heroes - Captain America (Chris Evans), Black Widow (Scarlett Johansson), Falcon (Anthony Mackie), Nick Fury (Samuel L. Jackson)

<p style="font-weight:bold;">Villains - Alexander Pierce (Robert Redford), The Winter Soldier (Sebastian Stan), Crossbones (Frank Grillo), Georges Batroc (Georges St-Pierre), Jasper Sitwell (Maximiliano Hernandez), Arnim Zola (Toby Jones)

Other Characters - Maria Hill (Cobie Smulders), Agent 13 (Emily McVamp)

The Amazing Spider-Man 2

Heroes - Spider-Man (Andrew Garfield)

Villains - Green Goblin (Dane DeHaan), Rhino (Paul Giamatti), Electro (Jamie Foxx)

Other Characters - Gwen Stacy (Emma Stone)

Guardians Of The Galaxy

Heroes - Star-Lord (Chris Pratt), Gamora (Zoe Saldana), Drax the Destroyer (Dave Bautista), Rocket Raccon (Bradley Cooper), Groot (Vin Diesal)

<p style="font-weight:bold;">Villains - Ronan (Lee Pace), Nebula (Karen Gillan), Thanos (Josh Brolin), The Other (Alexis Denisof), Korath (Djimon Hounsou), The Collector (Benicio del Toro),  Other Characters - Yondu (Michael Rooker), Carina (Ophelia Lovibond)

<h3 style="font-weight:bold;">2015

<p style="font-weight:bold;">Avengers: Age Of Ultron

Villains - Iron Man (Robert Downey Jr.), Captain America (Chris Evans), Hulk (Mark Ruffalo), Thor (Chris Hemsworth), Black Widow (Scarlett Johansson), Hawkeye (Jeremy Renner), Scarlet Witch (Elizabeth Olsen), Quicksilver (Aaron Taylor-Johnson), Vision (Paul Bettany), Iron Patriot (Don Cheadle), Falcon (Anthony Mackie), Black Panther (Chadwick Boseman), Ms. Marvel (TBA)

Villains - Ultron (James Spader), Baron von Strucker (Thomas Kretschmann), Thanos (Josh Brolin)

Other Characters - Maria Hill (Cobie Smublers), Peggy Carter (Hayley Atwell), Erik Selvig (Stellan Skarsgard), Pepper Potts (Gwyneth Paltrow), Jane Foster (Natalie Portman), Betty Ross (Liv Tyler), Agent 13 (Emily McVamp), Antione Triplett (B.J. Britt), Su Yin (Kim Soo Hyun)

<h3 style="font-weight:bold;">Phase 3

<p style="font-weight:bold;">Ant-Man

<p style="font-weight:bold;">Heroes - Ant-Man (Paul Rudd), The Wasp (Evangeline Lilly)

<p style="font-weight:bold;">Villains - Yellowjaket (Corey Stoll), Crossfire (David Dastmalchian)

Other Characters - Hank Pym (Michael Douglas), Cassie Lang (Abby Ryder Fortson), Janet van Dyne (Judy Greer)

<h3 style="font-weight:bold;">2016

<p style="font-weight:bold;">Captain America: Civil War

<p style="font-weight:bold;">Heroes - Captain America (Chris Evans), The Winter Soldier (Sebastain Stan),  Black Widow (Scarlett Johansson), Hawkeye (Jeremy Rener), Iron Man (Robert Downey Jr.), Mockingbird (Adrianne Palicki), Captain Marvel (TBA), Agent 13 (Emily VanCamp), Hulk (Mark Ruffalo), Maria Hill (Cobie Smulders), Nick Fury (Samuel L. Jackson), Falcon (Anthony Mackie), Phil Coulson (Clark Gregg), Melinda May (Ming-Na Wen), Skye (Chloe Bennet), Jemma Simmons (Elizabeth Henstridge), Antoine Triplett (B.J. Britt), Leo Fitz (Iain De Caestecker), Alphonso Mackenzie (Henry Simmons), Lance Hunter (Nick Blood), Daniel Whitehall (Reed Diamond), Billy Koening (Patton Oswalt), Deathlok (J. August Richards), Ms. Marvel (Aurora Fearnley)

<p style="font-weight:bold;">Villains - Crossbones (Frank Grillo), Red Skull (Hugo Weaving),  Baron Zemo  (TBA), M.O.D.O.K. (TBA), Wolfgang von Struker (Thomas Kretschmann)

<p style="font-weight:bold;">The Sinister Six

Heroes - Green Goblin (Dane DeHaan), Rhino (Paul Giamatti), Doctor Octopus (TBA), Mysterio (TBA), Kraven the Hunter (TBA), Vulture (TBA)

Villains: TBA

Doctor Strange

<p style="font-weight:bold;">Heores - Doctor Strange (Ethan Hawke)

<p style="font-weight:bold;">Villains - Baron Mordo (TBA), Dormammu (TBA)

2017
<p style="font-weight:bold;">Thor: Ragnarok

<p style="font-weight:bold;">Heroes - Thor (Chris Hemsworth), Beta Ray Bill (TBA)

Villains - Surtur (TBA), Enchantress (TBA), Excecutioner (TBA), Loki (Tom Hiddleston)

Guardians Of The Galaxy: War Of Kings

<p style="font-weight:bold;">Heroes - Star-Lord (Chris Pratt), Gamora (Zoe Saldana), Drax the Destoryer (Dave Bautista), Rocket Raccoon (Bradley Cooper), Groot (Vin Diesel), Adam Warlock (TBA)

<p style="font-weight:bold;">Villains - Korvac (TBA), Nebula (Karen Gillian), The Collector (Benicio del Toro)

<p style="font-weight:bold;">

2018
<p style="font-weight:bold;">

<p style="font-weight:bold;">Avengers: The Infinity Gauntlet

Heroes - Captain America (Sebastain Stan), Black Panther (Chadwick Boseman), Iron Man (Robert Downey Jr.), Thor (Chris Hemsworth), Hulk (Mark Ruffalo), Black Widow (Scarlett Johansson), Hawkeye (Jeremy Renner), Scarlet Witch (Elizabeth Olsen), Quicksilver (Aaron Taylor-Johnson), Vision (Paul Bettany), Mockingbird (Adrianne Palicki), Ant-Man (Paul Rudd), Wasp (Evangeline Lilly), Doctor Strange (Ethan Hawke), Ms. Marvel (Aurora Fearnly)

<p style="font-weight:bold;">Villains - Thanos (Josh Brolin), Baron von Strucker (Thomas Kretschman), Death (TBA), The Collector (Benicio del Toro)

<p style="font-weight:bold;">Hurt)

The Amazing Spider-Man 3

Heroes - Spider-Man (Candrew Garfield)

Villains: Rhino (Paul Giamatti), Green Goblin (Dane DeHaan)

Other Characters - Mary Jane Watson (Shailene Woodley), May Parker (Sally Field)

2019
<p style="font-weight:bold;">The Inhumans

Heroes - Black Bolt (Vin Diesal),  Medusa (Emily Blunt), Crystal (Saorise Ronan), Karnak (Luke Evans), Gorgon (Joe Mangiello), Triton (Alexander Skarsgard), Maximus (Iwan Rohen), Lockjaw (Bradley Dee Baker)

Villians - Skrulls (TBA)

Unknown Releases
  ' Black Panther' <p style="font-weight:bold;">Heroes - Black Panther (Chadwick Boseman)

<p style="font-weight:bold;">Villains - Erik Killmonger TBA), Klaw (TBA) World War Hulk <p style="font-weight:bold;">Heroes - Hulk (CGI Human: Mark Ruaffalo)

<p style="font-weight:bold;">Villians - TBA Ms. Marvel

Heroes - Ms. Marvel (Eden Sher), Captain Marvel (TBA)

Villians - Kree (TBA)

Black Widow 

<p style="font-weight:bold;">Heroes - Black Widow (Scarlett Johansson), Hawkeye (Jeremy Rener), Bucky Barnes (Sebastain Stan)

<p style="font-weight:bold;">Villains - HYDRA (Various Actors), Madame Hydra (TBA)

'''The Indestructible Hulk Heroes - Hulk (Mark Ruffalo), She-Hulk (Gretel Ashzinger), Doc Samson (Ty Burrell) '''

Villians - The Leader (Tim Blake Nelson), Red-Hulk (William 

Nova

Heroes - Nova (TBA)

Villians - Diamondhead (TBA), Sphinx (TBA)

Nick Fury

Heroes - Nick Fury (Samuel L. Jackson)

Villians - Baron von Struker (Thomas Kretchmann)

Guardians of the Galaxy 3

Heroes - Guardians of the Galaxy (Various Actors)

Villians - TBA

Black Cat

Heroes: Black Cat (Felicity Jones)

Villains: Kingpin (Vincent D'Onoforio)

Venom

Heroes - Venom (Finn Whitrock)

Villains: Carnage (Alan Tudyk)

Possible Movies
Vision

Ka-Zar (if not in X-Men universe)

Blade

The Punisher

Ghost Rider

Quasar

She-Hulk

2014
Agents of S.H.I.E.L.D 

Heroes - S.H.I.E.L.D (various actors)

Villlians - HYDRA (various actors)

2015
Agent Carter

Heroes - Peggy Carter (Hayley Atwell)

Villians - HYDRA (various actors)

2015
Daredevil

Heroes - Daredevil (Charlie Cox)

Villians - Kingpin (Vincent D'Onoforio), Bullseye (Craig Henningsen)

AKA Jessica Jones

Heroes - Jessica Jones (TBA), Luke Cage (Mars Crain)

Villians - Purple Man(TBA)

2016
Luke Cage

Heroes - Luke Cage (Mars Crain)

Villians - Chemistro (TBA)

Iron Fist

Heroes - Iron Fist (TBA)

Villians - Master Khan (TBA)

The Defenders

Heroes - The Defenders - Jessica Jones (TBA), Iron Fist (TBA), Luke Cage (Mars Crain), Daredevil (Charlie Cox)

Villians - Mephisto (TBA)

Characters
Avengers The Defenders
 * Chris Evans as Captain America (decreased)
 * Sabastain Stan as Captain America (current)
 * Robert Downey Jr. as Iron Man
 * Chris Hemsworth as Thor
 * Mark Ruffalo as Hulk
 * Scarlett Johansson as Black Widow
 * Jeremy Renner as Hawkeye
 * Elizabeth Olsen as Scarlet Witch
 * Aaron Taylor-Johnson as Quicksilver
 * Paul Bettany as The Vision
 * Chadwick Boseman as Black Panther
 * Joaquin Phonenix as Doctor Strange
 * Evangeline Lily as Wasp
 * Paul Rudd as Ant-Man
 * Eden Sher as Ms. Marvel
 * Anthony Mackie as Falcon
 * Don Cheadle as Iron Patriot
 * Chris Pratt as Star-Lord
 * Zoe Saldana as Gamora
 * Dave Bautista as Drax
 * Vin Diesel as Groot
 * Bradley Cooper as Rocket Raccoon
 * Charlie Cox as Daredevil
 * TBA as Jessica Jones
 * TBA as Iron Fist
 * Mars Crain as Luke Cage

Guardians of the Galaxy

 * Chris Pratt as Star-Lord
 * Zoe Saldana as Gamora
 * Dave Bautista as Drax
 * Bradley Cooper as Rocket Raccoon
 * Vin Diesal as Groot
 * TBA as Adam Warlock